ENCE 433
STOCHIOMETRY, EQUILIBRIUM AND THERMODYNAMICS
OBJECTIVES
At the conclusion of this section, given information on concentrations,
standard free energies of formation, Gof, standard
enthalpies of formation, Hof, and initial conditions,
you should be able to ...
- Balance a reaction
- Determine the amount of specific reactants a reaction needs to take
place to completion.
- Determine the number of moles and equivalents
- Determine the free energy change, DG, associated
with taking a system from one defined state to another (which might be
equilibrium).
- Determine the standard free energy change, DGrxno,
and the free energy change, DGrxn,
associated with a reaction.
- Predict which direction a reaction will proceed spontaneously, what
the stable phases will be when the system reaches equilibrium, and under
what conditions different solid phases can coexist.
- Determine the equilibrium constant, K, for a reaction, and determine
the effect of temperature on K.
- Determine the equilibrium composition of simple systems, including
the distribution of species among various phases.
ENCE 433
ACID-BASE CHEMISTRY
OBJECTIVES
At the conclusion of this section, you should be able to ...
- Recognize several common strong acids, bases, and electrolytes.
- Given concentrations, determine the equilibrium pH and composition
of a solution containing strong and/or weak acids and bases.
- Given pH, determine the composition (speciation) of a solution containing
strong and/or weak acids and bases.
- Write the system of equations needed to determine the speciation of
solutions containing acids and/or bases
- Construct pC-pH diagrams.
- Sketch the titration curve of a weak acid.
- Determine amount of acids/bases to neutralize a known waste
- Determine the amounts of acid/conjugate base needed to prepare buffer
solutions
- Identify the equivalence point(s) associated with a weak acid/base
and explain their physical significance.
- Determine the buffer capacity of a solution.
- Compare solutions of acids and bases and qualitatively rank them in
order of pH or buffer capacity.