ENCE 433
COMPLEXATION AND PRECIPITATION/DISSOLUTION
OBJECTIVES
At the conclusion of this section, you should be able to ...
- Determine the effect of a ligand on metal speciation
- Determine the effect of ligands on metal solubility
- Construct a solubility diagram for a mineral carbonate solid
or for a mineral hydroxide solid, in a closed or open system.
- Given initial conditions, determine whether a solution is
undersaturated, saturated, or oversaturated with respect to a
particular solid phase.
- If more than one solid phase is possible, predict which solid
phase controls or if two solid phases co-exist.
- Determine the equilibrium pH, alkalinity, and/or composition
of a solution when a solid phase may be present.
- Predict whether "solubility" and pH will increase,
decrease, or stay the same upon addition of strong or weak acid,
strong or weak base, salt, or one or more of the carbonate species.
- Recommend chemical additions (e.g., acid, base, complexing
agents, etc.) to achieve a desired total dissolved concentration
of a metal.